Black Angel
Arcane
Deep, deep down inside I actually kind of hold this view, with now Fallout 1.5: Resurrection being in a tie with New Vegas, simply by virtue of having party banter and how companions were handled in general. Sure, there's only very few of them, but party banter alone made it a tie, if not a bit better.FO1 > FO:NV > FO2
there aren't any others worth mentioning
Also, I personally hold FO1 as THE best Fallout, simply, because it ended with the protagonist turning his back to the camera and walking away, with Maybe by the Ink Spots playing in the background. What I mean by this, FO1 managed to give an such an excellent bitter-sweet ending that no longer evoked by even Fallout 2. Fallout 1.5 did an amazing job with its ending and I'll Never Smile Again by the Ink Spots playing in the background, fits so well just like how Maybe fits with FO1 ending.